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基于支持向量機(jī)的有機(jī)肥總養(yǎng)分含量NIRS分析
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“十一五”國(guó)家科技支撐計(jì)劃資助項(xiàng)目 (2006BAD07A13—2,、2006BAD10B05);高等學(xué)校博士學(xué)科點(diǎn)專項(xiàng)科研基金資助項(xiàng)目(20090008120008)


Near-infrared Reflectance Spectroscopy for Total Nutrient Analysis in Organic Fertilizer Using Linear Support Vector Machine
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    摘要:

    以我國(guó)22個(gè)省市的120份畜禽糞便為原料的有機(jī)肥產(chǎn)品樣品為研究對(duì)象,利用近紅外漫反射光譜法與支持向量機(jī)相結(jié)合建立了有機(jī)肥產(chǎn)品中總養(yǎng)分含量的快速測(cè)定模型,,并與偏最小二乘法所建模型作了比較,。利用偏最小二乘回歸法所建立的基于原始樣品和干燥粉碎樣品的總養(yǎng)分含量近紅外模型驗(yàn)證決定系數(shù)Rv2,、預(yù)測(cè)標(biāo)準(zhǔn)差SEP和驗(yàn)證相對(duì)分析誤差RPD分別為0.96,、7.95g/kg、2.47和0.93,、8.02g/kg,、3.58。利用支持向量機(jī)回歸法所建立的干燥粉碎樣品中總養(yǎng)分含量的近紅外模型驗(yàn)證決定系數(shù)Rv2,、預(yù)測(cè)標(biāo)準(zhǔn)差SEP和驗(yàn)證相對(duì)分析誤差RPD分別為0.93,、7.38g/kg和3.88。結(jié)果表明,,近紅外漫反射光譜法可以快速測(cè)定畜禽糞便為原料的有機(jī)肥產(chǎn)品中總養(yǎng)分含量,,與偏最小二乘法相比,支持向量機(jī)所建模型具有更高的預(yù)測(cè)精度,。

    Abstract:

    A new method was explored to predict the total nutrient content in organic fertilizer products using near-infrared reflectance spectroscopy (NIRS) with linear support vector machine regression (SVR), compared with partial least-squares regression (PLSR). 120 commercial organic fertilizer samples were collected from 22 provinces in China. Spectra of orient and dried (passed 1 mm screen) samples were scanned with a SPECTRUM ONE NTS (PerkinElmer, New Jersey, USA) from 10000 to 4000cm-1,respectively. NIRS—PLSR models for total nutrient in organic fertilizer products samples on orient and dried basis were developed with the following results: the determination coefficient of validation (Rv2), the standard error of prediction (SEP) and RPD (SD/SEP) on orient and dried basis were 0.96, 7.95g/kg,2.47 and 0.93, 8.02g/kg, 3.58, respectively. The validation results of NIRS—SVR model for total nutrient content on dried basis were Rv2 0.93, SEP 7.38g/kg and RPD 3.88.Results showed the feasibility and potential of NIRS to predict total nutrient content in organic fertilizer products, and NIRS-SVR method on dried basis is the best choice.

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黃光群,王曉燕,韓魯佳.基于支持向量機(jī)的有機(jī)肥總養(yǎng)分含量NIRS分析[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2010,41(2):93-98. Huang Guangqun, Wang Xiaoyan, Han Lujia. Near-infrared Reflectance Spectroscopy for Total Nutrient Analysis in Organic Fertilizer Using Linear Support Vector Machine[J]. Transactions of the Chinese Society for Agricultural Machinery,2010,41(2):93-98.

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