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基于反應(yīng)過程堿液電導(dǎo)率變化的食用油酸值檢測(cè)
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中央高校基本科研業(yè)務(wù)費(fèi)專項(xiàng)資金資助項(xiàng)目(QN2009074)


Determination of Acid Value of Edible Oils Based on Electrical Conductivity Change Value of Alkaline Solution during Reaction
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    摘要:

    以食用油為試驗(yàn)材料,,建立基于堿液與食用油混合反應(yīng)過程堿液電導(dǎo)率變化的食用油脂酸值檢測(cè)方法,,并探討堿液濃度,、靜置時(shí)間,、油脂種類,、溫度,、料液比等對(duì)測(cè)定結(jié)果的影響,,建立了酸值模型,進(jìn)行了模型的驗(yàn)證,。結(jié)果表明:檢測(cè)條件變化對(duì)測(cè)定結(jié)果影響均不顯著,;料液比為1∶10時(shí),食用油酸值模型為y=0.0024x-0.1571(y為酸值,;x為電導(dǎo)率變化值),,R2=0.9984。模型預(yù)測(cè)值與國(guó)標(biāo)法測(cè)定的酸值高度線性相關(guān),,盲樣驗(yàn)證相對(duì)誤差均小于10%,。

    Abstract:

    The electrical conductivity method for determination of acid value in edible oil was developed based on the electrical conductivity change value of alkaline solution during reaction, and the effects on determination of the varying condition, as concentration of the alkaline solution, types of the oil samples, temperature and the solid-liquid ratio were explored. The method was validated by Chinese national standard methods. The results showed the experimental conditions had no significant effect on the determination. When the solid-liquid ratio was 1∶10, the calibration was y=0.0024x-0.1571 (where x is the value of the conductivity change, y is acid values), R2=0.9984. The linear correlativity of the determination of the acid value between two methods was very well, the relative deviation of blind samples experiment’s data were less than 10%.

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于修燭,楊晨,杜雙奎,高錦明.基于反應(yīng)過程堿液電導(dǎo)率變化的食用油酸值檢測(cè)[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2011,42(9):146-150. Yu Xiuzhu, Yang Chen, Du Shuangkui, Gao Jinming. Determination of Acid Value of Edible Oils Based on Electrical Conductivity Change Value of Alkaline Solution during Reaction[J]. Transactions of the Chinese Society for Agricultural Machinery,2011,42(9):146-150.

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