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基于電化學(xué)和虛擬儀器的土壤重金屬檢測系統(tǒng)研究
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國家高技術(shù)研究發(fā)展計劃(863計劃)資助項目(2011AA100704)和高等學(xué)校博士學(xué)科點專項科研基金資助項目(20120008110033)


Detection System of Heavy Metals in Soil Based on Electrochemistry and Virtual Instrument
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    摘要:

    采用超聲波輔助提取法對土壤樣本進(jìn)行快速前處理,以鉍膜修飾絲網(wǎng)印刷電極作為傳感器,結(jié)合差分脈沖陽極溶出伏安法對土壤浸提液中的鉛和鎘進(jìn)行精確測量。檢測儀器以LabView平臺軟件為工作核心,,結(jié)合MSP430單片機、恒電位電路,、I/V轉(zhuǎn)換電路,、電磁閥和蠕動泵等硬件設(shè)備實現(xiàn)了對土壤浸提液的自動進(jìn)樣,、電化學(xué)分析以及排液清洗等鉛和鎘的操作,。針對實際土壤樣本測量時可能產(chǎn)生的誤差,,分別采用了概率統(tǒng)計算法以及多次標(biāo)準(zhǔn)添加法加以消除。系統(tǒng)檢測限分別達(dá)到2.6μg/L和1.8μg/L,。對不同地區(qū)采集到的多個土壤樣本進(jìn)行分析,,結(jié)果表明該系統(tǒng)具有檢測精度高、重現(xiàn)性好,、速度快,、功耗低等優(yōu)點,,適合對農(nóng)田土壤重金屬進(jìn)行快速檢測和評估,。

    Abstract:

    A detection system for rapid monitoring heavy metals in soil based on electrochemical and virtual instrument technology was developed. The ultrasonic-assistant extraction technique was used for rapid pretreatment of soil samples. Single use sensors bismuth film modified screen-printed electrodes coupled with differential pulse anodic stripping voltammetry (DPASV) provided a rapid, accurate screening system for the simultaneous determination of cadmium and lead in soil. The control program, developed in LabView, was adopted as control kernel, by combining the MSP430 microcontroller, the potentiostat circuit, I/V conversion circuit, peristaltic pump and electromagnetic valve. This system realized the automatic measurement. The probability statistics algorithms and the standard addition method were employed to overcome the inherent measurement errors existed in real soil analysis and the system detection limits were 1.8μg/L for cadmium and 2.6μg/L for lead, respectively. Experimental results showed that the system possesses many advantages such as high precision, good reproducibility, high speed and low power consumption, which was suitable for rapid evaluation and measurement of heavy metals in soil.

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王志強,王 輝,張志豪,劉 剛,姚艷芝.基于電化學(xué)和虛擬儀器的土壤重金屬檢測系統(tǒng)研究[J].農(nóng)業(yè)機械學(xué)報,2015,46(1):119-126. Wang Zhiqiang, Wang Hui, Zhang Zhihao, Liu Gang, Yao Yanzhi. Detection System of Heavy Metals in Soil Based on Electrochemistry and Virtual Instrument[J]. Transactions of the Chinese Society for Agricultural Machinery,2015,46(1):119-126.

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  • 收稿日期:2014-03-17
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  • 在線發(fā)布日期: 2015-01-10
  • 出版日期: 2015-01-10
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