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麥稈濕解固體產(chǎn)物腐殖化與炭化特性分析
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國家自然科學基金資助項目(51206194)


Analysis on Humification and Carbonization Characteristic of Solid Products from Hydrothermal Treated Wheat Straw
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    摘要:

    為了研究生物質(zhì)濕解過程中固體產(chǎn)物的腐殖化和炭化特性,,以麥稈為原料,,在高溫高壓反應(yīng)釜中,進行反應(yīng)溫度為220℃,、停留時間30~180min條件下的濕解實驗研究,,結(jié)合X射線衍射(XRD)和傅里葉紅外光譜(FTIR)檢測分析結(jié)果對麥稈濕解固體產(chǎn)物的微觀結(jié)構(gòu)和化學組成進行了深入分析,。研究發(fā)現(xiàn),麥稈經(jīng)過濕解處理,,固體產(chǎn)物中C元素質(zhì)量分數(shù)從停留時間30min時的45.86%逐漸增加至180min時的49.06%,;在停留時間為60min時,XRD譜圖上在衍射角2θ約為26°附近就已經(jīng)出現(xiàn)強峰,,微晶結(jié)構(gòu)接近于石墨,并隨停留時間的增加,,芳香化和炭化程度逐漸提高,;固體產(chǎn)物中含有豐富的腐殖質(zhì),具有大量的芳香結(jié)構(gòu)和含氧官能團,。

    Abstract:

    Hydrothermal treatment (HTT) is a promising process for conversing lignocellulosic biomass into solid fuel with higher carbon content. To investigate humification and carbonization characteristic of solid products from biomass HTT, the hydrothermal experiments were carried out in an autoclave using wheat-straw as raw materials at temperature 220℃. The residence time were set as 30, 60, 90, 120 and 180min, respectively. The micro-structure and chemical composition of solid products were analyzed by using X-ray diffraction (XRD) and Fourier transform infrared (FTIR). The experimental results showed that the carbon content in the solid increased from 45.86% for 30 min to 49.06% for 180min. There was a strong peak in the diffraction angle 2θ of 26° in the XRD spectrum at residence time 60min. The microcrystalline structure of the solid approached to that of graphite. With the residence time increasing, the degree of aromatization and carbonization increased. The solid products contained numerous humus, had plenty of aromatic structure and oxygen functional groups. Longer residence time was favorable for raising the extent of carbonization of solid products during biomass HTT. The research results provided a data reference for the fundamental process control and improvements of hydrothermal carbonization of biomass.

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郭淑青,董向元,劉開拓.麥稈濕解固體產(chǎn)物腐殖化與炭化特性分析[J].農(nóng)業(yè)機械學報,2015,46(1):180-184. Guo Shuqing, Dong Xiangyuan, Liu Kaituo. Analysis on Humification and Carbonization Characteristic of Solid Products from Hydrothermal Treated Wheat Straw[J]. Transactions of the Chinese Society for Agricultural Machinery,2015,46(1):180-184.

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  • 收稿日期:2014-02-27
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  • 在線發(fā)布日期: 2015-01-10
  • 出版日期: 2015-01-10
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