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陜西某關(guān)閉冶煉廠土壤重金屬污染評價與工程修復(fù)
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國家自然科學(xué)基金資助項目(41101288),、中央高?;究蒲袠I(yè)務(wù)費專項資金資助項目(2014YB064)和西北農(nóng)林科技大學(xué)博士科研啟動專項資助項目(2013BSJJ120)


Heavy Metals Polluted Soil Environment Assessment and Engineering Remediation Practice in Closed Smelter in Shaanxi Province Remediation Practice in Closed Smelter in Shaanxi Province
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    摘要:

    實地采集了15個土壤剖面樣品,,并對其中的Pb,、Cd,、Hg,、As,、Cu、Cr,、Zn和Ni含量進(jìn)行分析監(jiān)測,,采用潛在生態(tài)危害風(fēng)險評價法對研究區(qū)域土壤中重金屬的污染狀況進(jìn)行了評價,并通過工程措施進(jìn)行了污染土壤修復(fù)治理,。結(jié)果表明,,在0~20 cm土層范圍內(nèi),Zn質(zhì)量比在89.80~724.03 mg/kg之間,,Cu質(zhì)量比在28.89~1 271.81 mg/kg之間,,Hg質(zhì)量比介于0.04~4.48 mg/kg之間,Pb質(zhì)量比介于48.69~12 021.15 mg/kg之間,。Cd質(zhì)量比在0~120 cm范圍內(nèi)均超過了土壤環(huán)境質(zhì)量二級標(biāo)準(zhǔn),,而且Pb、Cd,、Hg,、Cu和Zn在0~120 cm范圍內(nèi)全部超過了關(guān)中塿土背景值。潛在生態(tài)危害風(fēng)險評價表明,,Cd的潛在生態(tài)危害系數(shù)范圍為26.0~21 118.6,,輕微、中等,、較強(qiáng),、很強(qiáng)和極強(qiáng)的生態(tài)危害頻率分別為4.3%、15.2%,、19.6%,、15.2%和37%,;Pb的潛在生態(tài)危害系數(shù)范圍為0.1~120.2,輕微,、中等和較強(qiáng)的生態(tài)危害頻率分別為93.5%,、4.3%和2.2%;Hg的潛在生態(tài)危害系數(shù)范圍為0.1~83.4,,輕微,、中等和較強(qiáng)的生態(tài)危害頻率分別為59.3%、39.4%和1.3%,;As、Ni,、Zn和Cu均具有輕微生態(tài)危害,。研究區(qū)域土壤重金屬污染主要是Cd、Hg和Pb等形成的復(fù)合污染,。采用原位挖掘-異位固化-客土回填法,,對研究區(qū)域進(jìn)行污染土壤工程修復(fù),可獲得良好的修復(fù)效果,。

    Abstract:

    To remediate the heavy metals polluted soil around a closed smelter in Shaanxi Province, 15 soil profile samples were collected in the site and analyzed for heavy metals content, including Pb, Cd, Hg, As, Cu, Cr, Zn and Ni. The pollution situation was assessed by using the ecological hazard risk assessment method, and the contaminated soil was finally remediated by in-situ replacement engineering methods. The results showed that within top 0~20 cm soil layer, Zn contents ranged from 89.80 mg/kg to 724.03 mg/kg, Cu contents varied from 28.89 mg/kg to 1 271.81 mg/kg, Hg contents changed from 0.04 mg/kg to 4.48 mg/kg,,and the Pb contents were around 48.69~12 021.15 mg/kg. Cd contents in the top soil layer of 0~120 cm were above the secondary standard value of soil environment quality, while Pb, Cd, Hg, Cu and Zn contents in soil within 0~120 cm were higher than those of the Lou soil background values. The results of potential ecological risk implicated that the potential ecological risk factor for Cd ranged from 26.0 to 21 118.6, and its slight, moderate, strong, very strong and extremely strong ecological hazards frequencies were 4.3%, 15.2%, 19.6%, 15.2% and 37%, respectively. The potential ecological risk factor of Pb ranged from 0.1 to 120.2, and its slight, moderate and strong ecological hazards frequencies were 93.5%, 4.3% and 2.2%, respectively. The potential ecological risk factor of Hg ranged from 0.1 to 83.4, and its slight, moderate and strong ecological hazards frequencies were 59.3%, 39.4% and 1.3%, respectively. Elements As, Ni, Zn and Cu, all had slight ecological hazards. The soil heavy metals pollution in the study area was mainly contributed by Cd, Pb and Hg. The in-situ replacement method was proved to be an efficient method for the smelter polluted soil remediation and it could achieve satisfactory performance.

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李榮華,馮靜,李曉龍,張增強(qiáng),沈鋒,李念.陜西某關(guān)閉冶煉廠土壤重金屬污染評價與工程修復(fù)[J].農(nóng)業(yè)機(jī)械學(xué)報,2015,46(10):223-228. Li Ronghua, Feng Jing, Li Xiaolong, Zhang Zengqiang, Shen Feng, Li Nian. Heavy Metals Polluted Soil Environment Assessment and Engineering Remediation Practice in Closed Smelter in Shaanxi Province Remediation Practice in Closed Smelter in Shaanxi Province[J]. Transactions of the Chinese Society for Agricultural Machinery,2015,46(10):223-228.

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  • 收稿日期:2015-03-18
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  • 在線發(fā)布日期: 2015-10-10
  • 出版日期: 2015-10-10
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