ass日本风韵熟妇pics男人扒开女人屁屁桶到爽|扒开胸露出奶头亲吻视频|邻居少妇的诱惑|人人妻在线播放|日日摸夜夜摸狠狠摸婷婷|制服 丝袜 人妻|激情熟妇中文字幕|看黄色欧美特一级|日本av人妻系列|高潮对白av,丰满岳妇乱熟妇之荡,日本丰满熟妇乱又伦,日韩欧美一区二区三区在线

微波輔助生物質(zhì)焦炭誘導(dǎo)甲苯裂解和重整試驗
CSTR:
作者:
作者單位:

作者簡介:

通訊作者:

中圖分類號:

基金項目:

“十二五”國家科技支撐計劃資助項目(2014BAC26B03-02),、山東省優(yōu)秀中青年科學(xué)家科研獎勵基金資助項目(BS2014NJ014)和山東科技大學(xué)人才引進科研啟動基金資助項目(2013RCRCJJ018)


Toluene Cracking and Reforming over Biomass-derived Char under Microwave Heating under Microwave Heating
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 圖/表
  • |
  • 訪問統(tǒng)計
  • |
  • 參考文獻
  • |
  • 相似文獻
  • |
  • 引證文獻
  • |
  • 資源附件
  • |
  • 文章評論
    摘要:

    選用甲苯模擬焦油芳香環(huán)物質(zhì),,研究微波輔助生物質(zhì)焦炭誘導(dǎo)甲苯裂解和重整反應(yīng)規(guī)律,、產(chǎn)物特性和焦炭變化。試驗結(jié)果表明,焦炭對甲苯裂解有催化作用,,微波環(huán)境易于甲苯裂解。甲苯裂解率和氫氣選擇性與溫度正相關(guān),750℃是適宜的溫度選項,,此溫度下裂解率與氫氣選擇性分別為92.77%和91.94%,此后無明顯變化,。通入CO2促使甲苯重整制備合成氣,,700℃最高轉(zhuǎn)化率92.03%和最大合成氣收率91.30%均在CO2流量為80 mL/min時實現(xiàn),H2/CO值隨CO2流量的加大而降低直至0.22,。通入CO2導(dǎo)致焦炭碳質(zhì)量變化率增加,,700℃最高達5.42%,此部分碳轉(zhuǎn)化合成氣,,對合成氣產(chǎn)率的貢獻率最高可達15.40%,。通入CO2可減緩積碳對甲苯轉(zhuǎn)化的不利影響。

    Abstract:

    From the point of developing a new approach for the disposal of tar derived from biomass gasification, microwave-assisted tar cracking and reforming were performed over a biomass-derived char, with toluene as a model compound of tar aromatic substances. And the reaction rules, production distribution and changes of biomass char in process of toluene cracking and reforming were studied. The results indicated that biomass char had a catalytic effect on toluene cracking, and it was approved that microwave heating could favor toluene cracking. By analyzing the results, it was observed that toluene conversion and hydrogen selectivity were directly correlated to bed temperature in cracking reaction. Toluene cracking was optimized at 750℃, and the greatest toluene conversion and hydrogen selectivity were obtained, which were 92.77% and 91.94%, respectively. Afterwards, changes in toluene conversion and hydrogen selectivity were insignificant. It was further revealed that the introduction of CO2 could reform toluene into syngas production. At 700℃, the highest conversion rate of 92.03% was reached at CO2 flow rate of 80 mL/min, accompanied by a maximal syngas yiled rate of 91.30%. And increasing CO2 flow rate decreased the ratio of H2 to CO dramatically. The lowest ratio of 0.22 was obtained at CO2 flow rate of 120 mL/mm. The introduction of CO2 also brought about a loss of carbon in biomass char. And carbon loss was maximized to 5.42% at 700℃. At the same time, the depleted carbon was further converted into additional syngas production, which provided the highest contribution of 15.40% for total syngas production. Finally, it was demonstrated that an excess of CO2 could slow down the negative effect of carbon deposition on toluene conversion.

    參考文獻
    相似文獻
    引證文獻
引用本文

李龍之,宋占龍,馬春元,趙希強,王孚懋,孔祥強.微波輔助生物質(zhì)焦炭誘導(dǎo)甲苯裂解和重整試驗[J].農(nóng)業(yè)機械學(xué)報,2015,46(10):229-234,303. Li Longzhi, Song Zhanlong, Ma Chunyuan, Zhao Xiqiang, Wang Fumao, Kong Xiangqiang. Toluene Cracking and Reforming over Biomass-derived Char under Microwave Heating under Microwave Heating[J]. Transactions of the Chinese Society for Agricultural Machinery,2015,46(10):229-234,303.

復(fù)制
分享
文章指標
  • 點擊次數(shù):
  • 下載次數(shù):
  • HTML閱讀次數(shù):
  • 引用次數(shù):
歷史
  • 收稿日期:2015-01-12
  • 最后修改日期:
  • 錄用日期:
  • 在線發(fā)布日期: 2015-10-10
  • 出版日期: 2015-10-10
文章二維碼