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熱解揮發(fā)物分級冷凝初分生物油研究
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農(nóng)業(yè)科技成果轉(zhuǎn)化項(xiàng)目(2014GB2E000048)和廣東省應(yīng)用型科技研發(fā)專項(xiàng)(20150237)


First-fractional Bio-oil by Fractional Condensation of Pyrolysis Volatiles
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    摘要:

    設(shè)計(jì)了一種恒溫分級冷凝裝置,應(yīng)用該裝置對油茶果殼在500℃時(shí)的熱解揮發(fā)物進(jìn)行了分級冷凝試驗(yàn),,獲得了165℃以上,、165~120℃、120℃以下3個(gè)冷凝溫度段下的分級生物油產(chǎn)物,;分析了各組產(chǎn)物的熱值,、pH值,、運(yùn)動(dòng)粘度后發(fā)現(xiàn):前2級生物油產(chǎn)物的含水率得到了有效降低,,高位熱值均大于23MJ/kg,比常規(guī)方法所獲生物油的熱值增加約44%,,但運(yùn)動(dòng)粘度較大,;隨著冷凝溫度的降低,各組生物油運(yùn)動(dòng)粘度顯著下降,,pH值略有提升,;通過熱分析曲線并結(jié)合綜合燃燒特性指數(shù)分析了生物油的燃燒特性,發(fā)現(xiàn)利用分級冷凝所獲得的初分生物油在燃燒特性上出現(xiàn)了比較明顯的區(qū)別,,其中第2級生物油在各組樣品中的燃燒性能最好,。試驗(yàn)結(jié)果表明,所設(shè)計(jì)的分級冷凝裝置基本實(shí)現(xiàn)了熱解揮發(fā)物的在線初級分離,,各級產(chǎn)物的特性有比較明顯的區(qū)別,,為生物油分級冷凝裝置的設(shè)計(jì)提供了參考,為分級生物油的進(jìn)一步應(yīng)用奠定了基礎(chǔ),。

    Abstract:

    Pyrolysis is an important way of biomass resources utilization. As a liquid product of biomass pyrolysis, biooil has good application prospects in future energy market. However, the problems of low calorific value, high viscosity, high moisture content, high corrosiveness, and poor stability problem exist until now, which constrain further application of biooil. At present, many scholars at home and abroad focus on staged utilization of biooil, by different separation methods to yield the biooils with diverse physical and chemical properties, and then by further purification to obtain the high quality of biooil. Fractional condensation can realize realtime primary separation of biooil, which can facilitate further refinement, so the field has become research focus. In order to achieve the fractional condensation of biooil,,various condensation modes were studied in worldwide. Spray condensation were widely used to achieve the aim of rapid condensation because it can quickly reduce the temperature of pyrolysis gas. The tube condensation mainly depending on indirect heat transfer was used in largescale chemical production and its technology was mature, so tube condensation was applied to the research of fractional condensation. Based on the previous researches on fractional condensation unit, a fractional condensation unit using constant temperature condensation was designed, of which condensation levels and heat exchange area can be adjusted flexibly. By the independent design of multilevel condensing unit and adopting camellia seed shells as pyrolysis materials, fractional condensation tests on the pyrolysis volatiles of camellia seed shells at 500℃ were carried out, and three fractional biooil products under the condensation temperature levels of more than 165℃ and 165~120℃, below 120℃ were received. The physical and chemical characteristics of the products were analyzed, and the analysis results of the first two levelfractional products at more than 165℃, 165~120℃ showed that moisture content effectively reduced and gross calorific value was more than 23MJ/kg on average, 44% more than the calorific value obtained by conventional condensation, but kinematic viscosity was not improved. With condensation temperature dropped, kinematic viscosity had significant reduction in each group of biooil and pH value was slightly rose. Combining the thermal analysis curves with comprehensive combustion characteristic index to analyze combustion characteristics of biooil, the results showed that biooils of primary separation obtained by fractional condensation had obvious differences, and YY2 demonstrated the best combustion performance. In conclusion, realtime primary separation of pyrolysis volatiles generally was achieved by dependently designed fractional condensation and the characteristics of each stage’s product were varied. The device designed can provide a reference for design of fractional condensation of pyrolysis volatiles and lay a theoretical foundation for the further application of fractional biooil.

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韓平,蔣恩臣,李世博,王明峰,孫焱,吳宇健.熱解揮發(fā)物分級冷凝初分生物油研究[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2016,47(11):207-212. Han Ping, Jiang Enchen, Li Shibo, Wang Mingfeng, Sun Yan, Wu Yujian. First-fractional Bio-oil by Fractional Condensation of Pyrolysis Volatiles[J]. Transactions of the Chinese Society for Agricultural Machinery,2016,47(11):207-212.

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  • 收稿日期:2016-01-01
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  • 在線發(fā)布日期: 2016-11-10
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