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仿箬葉聚合物表面模板法制備與潤濕性能研究
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國家自然科學(xué)基金青年科學(xué)基金項目(51305465)和中南大學(xué)研究生自主探索創(chuàng)新項目(2016zzts309)


Replication by Template Methods and Wetting Properties of Indocalamus-leaf-like Polymer Surfaces
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    摘要:

    從師法自然出發(fā),,以靜態(tài)接觸角高達140°的箬葉下表面為仿生對象,,使用2種模板法制備具有箬葉下表面微納復(fù)合結(jié)構(gòu)的聚合物仿生表面,。采用掃描電鏡觀測聚合物仿生表面的微觀形貌,,借助接觸角測量儀分析仿生表面的潤濕性能,。以箬葉下表面為模板,,采用聚二甲基硅氧烷(PDMS)二次復(fù)形方法獲得仿箬葉下表面,,僅實現(xiàn)微乳突結(jié)構(gòu)的部分復(fù)形,,而大多數(shù)納米片層結(jié)構(gòu)缺失,,其靜態(tài)接觸角與PDMS本征接觸角相比只提高了7°左右,。采用電鑄與注射成型相結(jié)合的方法獲得的仿箬葉聚丙烯(PP)表面,可基本實現(xiàn)微納復(fù)合結(jié)構(gòu)的復(fù)形,,其靜態(tài)接觸角與PP本征接觸角相比提高了50°以上,,進一步采用低表面能的氟硅烷修飾注射成型仿箬葉PP表面,其靜態(tài)接觸角與PP本征接觸角相比提高了70°左右,,達到了133°±2°,。但2種模板法成型的仿生聚合物表面均未能較好保留箬葉的動態(tài)潤濕性能。實驗結(jié)果表明,,通過電鑄-注射法構(gòu)筑仿箬葉表面的微納復(fù)合結(jié)構(gòu),、在粗糙表面上修飾低表面能物質(zhì)的雙重途徑可用于實現(xiàn)仿生疏水表面高效低成本的制備。

    Abstract:

    Learn from the nature, the undersurface of indocalamus leaf with water contact angle of 140° was taken as the mimetic object. Two template methods were chosen to fabricate polymer biomimetic surfaces which had the similar micro-nano hierarchical structure characteristics of the indocalamus leaf. The morphology and surface wettability of polymer biomimetic surfaces were investigated by scanning electron microscope and contact angle meter, respectively. The undersurface of indocalamus leaf was then used as a template. Only some replicated micro-papilla were found on the PDMS biomimetic surface fabricated by a double replica method, missing most nano-lamellar structures. The water contact angle of PDMS biomimetic surface was only increased by 7°, compared with that of PDMS flat surface. The PP biomimetic surfaces were fabricated by injection molding combined with electroforming process. Results showed that the most micro-nano hierarchical structures of indocalamus leaf were successfully transferred onto the PP surfaces. Compared with PP flat surface, the water contact angle of PP biomimetic surface was increased by 50°. The PP biomimetic surface was then modified by fluoroalkylsilane with low surface energy. Compared with PP flat surface, the water contact angle of modified PP biomimetic surface was increased by 70°, reaching 133°±2°. But the polymer biomimetic surfaces fabricated by these two template methods can not reserve the dynamic wettability of natural indocalamus leaf. Results showed that the injection molding combined with electroforming and modification by fluorochemicals could be used to fabricate biomimetic hydrophobic surfaces with high efficiency and low cost.

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翁燦,楊冬嬌,王飛,周宏慧.仿箬葉聚合物表面模板法制備與潤濕性能研究[J].農(nóng)業(yè)機械學(xué)報,2017,48(10):424-428. WENG Can, YANG Dongjiao, WANG Fei, ZHOU Honghui. Replication by Template Methods and Wetting Properties of Indocalamus-leaf-like Polymer Surfaces[J]. Transactions of the Chinese Society for Agricultural Machinery,2017,48(10):424-428.

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  • 收稿日期:2017-01-23
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  • 在線發(fā)布日期: 2017-10-10
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