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桉樹(shù)熱解產(chǎn)物熱物性參數(shù)演變特性研究
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國(guó)家自然科學(xué)基金項(xiàng)目(51706074),、科技部農(nóng)業(yè)科技成果轉(zhuǎn)化資金項(xiàng)目(20150237)、廣州市科技計(jì)劃項(xiàng)目(201607010138)和廣東省科技計(jì)劃項(xiàng)目(20160221)


Thermal Parameters Properties Evolution of Eucalyptus Pyrolysis Bio-char
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    摘要:

    在自行設(shè)計(jì)的生物質(zhì)固定床熱解裝置上,進(jìn)行了150~850℃溫度范圍內(nèi),每隔100℃的桉樹(shù)芯材木屑的固定床熱解實(shí)驗(yàn),并進(jìn)行固態(tài)產(chǎn)物的熱物性參數(shù)測(cè)試,。結(jié)果表明:隨著溫度的升高,,桉樹(shù)芯材熱解炭的固態(tài)產(chǎn)率逐漸減小,,低位熱值逐漸增大,,450℃熱解炭的熱值比木屑原料提高了95.53%,;堆積密度先減小后增大,體積能量密度持續(xù)增大,,750℃熱解炭的體積能量密度比原料增大了63.21%,;熱解炭的比熱容和導(dǎo)熱系數(shù)與熱解炭?jī)?nèi)部的含水率、骨架結(jié)構(gòu),,即孔道開(kāi)度和密度有密切的關(guān)系,。隨著熱解溫度的升高,熱解炭的比熱容呈U字型趨勢(shì)先減小而后增大,,導(dǎo)熱系數(shù)先輕微減小后以指數(shù)形式大幅增大,,得到比熱容和導(dǎo)熱系數(shù)隨溫度的變化曲線方程,擬合度分別為0.9320和0.9953,。

    Abstract:

    In recent years, with the growth of population and shortage of fossil energy, the environmental pollution problem has become more severe. Eucalyptus planted in south China is a kind of biomass resource with large quantity and high quality. The thermochemical conversion of biomass (pyrolysis, gasification, or combustion) is one of the most promising non-nuclear forms of future energy. It is a renewable source of energy and has many advantages from the ecological point of view. Pyrolysis of wood is a very complicated physical and chemical process which can transform biomass into useful fuel, such as bio-char, bio-oil and gas. Studying its thermo-physical properties is of great significance for the design of the equipment, control of process parameters and quality of the product. In the self-designed fixed bed pyrolysis device, the eucalyptus wood chips were paralyzed in the temperature range of 150~850℃. The remaining bio-char proceeds to be tested for the thermal parameters, including solid yield, bulk density, volume energy density, specific heat and heat conductivity coefficient. The results showed that with the increase of temperature, the solid yield was decreased and the weight loss rate in temperature range of 150~350℃ was up to 31.40% per 100℃;the lower heating value (LHV) of samples was increased gradually. The LHV of bio-char at 750℃ was 95.53% higher than that of the raw eucalyptus. Bulk density was decreased first and then increased while the volume energy density (VED) was increased in the whole experimental temperature range. The VED of bio-char at 750℃ was up to 63.21% more intensive than the raw material. The specific heat and heat conductivity coefficient were closely related to the moisture content and pores structure in bio-char. With the increase of treated temperature, the specific heat of sample presented a U-shaped tendency which was decreased firstly and then increased significantly. The heat conductivity coefficient was increased according to exponential growth after slight decrease. The fitting equations of specific heat Cp and heat conductivity coefficient λ with temperature were obtained and the fitting degrees R2 were 0.9320 and 0.9953, respectively.

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王明峰,陳志文,蔣恩臣,任永志,王東海,王微.桉樹(shù)熱解產(chǎn)物熱物性參數(shù)演變特性研究[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2018,49(3):317-321. WANG Mingfeng, CHEN Zhiwen, JIANG Enchen, REN Yongzhi, WANG Donghai, WANG Wei. Thermal Parameters Properties Evolution of Eucalyptus Pyrolysis Bio-char[J]. Transactions of the Chinese Society for Agricultural Machinery,2018,49(3):317-321.

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  • 收稿日期:2017-11-11
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  • 在線發(fā)布日期: 2018-03-10
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