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基于NTP的生物質(zhì)熱解氣間接加氫提質(zhì)試驗(yàn)研究
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國(guó)家自然科學(xué)基金項(xiàng)目(51806186),、國(guó)家留學(xué)基金項(xiàng)目(201908320111)和鹽城工學(xué)院引進(jìn)人才校級(jí)科研基金項(xiàng)目(XJ201708)


Experiment on Indirect Hydrogenation Upgrading of Biomass Pyrolysis Vapors Based on NTP
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    摘要:

    為提高生物質(zhì)熱解氣的提質(zhì)轉(zhuǎn)化效率,,以聚乙烯塑料熱解氣為間接加氫原料,利用低溫等離子體(Nonthermal plasma, NTP)協(xié)同Ru,、Ti及Sn改性HZSM-5,,間接加氫生物質(zhì)熱解氣制備烴類燃料,探討了金屬改性對(duì)反應(yīng)中活性自由基,、有機(jī)相產(chǎn)率,、理化特性與化學(xué)組成以及催化劑結(jié)焦率的影響,。結(jié)果表明,在NTP條件下,,Ru和Ti改性可以活化熱解氣,,形成更多同尺度活性自由基,有利于混合熱解氣的有效整合,,其中,,Ti改性使有機(jī)相產(chǎn)率和高位熱值分別達(dá)到58.73%和38.73MJ/kg;Ru,、Ti和Sn改性使有機(jī)相中芳香烴相對(duì)含量顯著升高,,升幅分別為109.15%、208.55%和52.52%,,Ru和Ti改性導(dǎo)致產(chǎn)物有效氫碳比降低;Ru,、Ti和Sn改性催化劑的結(jié)焦率從12.88%分別降至9.44%,、4.95%和10.91%,Ti改性催化劑具有較高的穩(wěn)定性,。研究表明,,在NTP作用下,Ti改性HZSM-5對(duì)混合熱解氣具有較高的提質(zhì)轉(zhuǎn)化效率,,且催化穩(wěn)定性較高,。

    Abstract:

    In order to effectively improve the upgrading efficiency of biomass pyrolysis vapors, polyethylene pyrolysis volatiles were used as indirect hydrogenation material, and indirect hydrogenation upgrading of biomass pyrolysis vapors was conducted over HZSM-5 and its Ru, Ti and Sn modified versions to prepare biofuels. Besides, non-thermal plasma (NTP) technology was introduced to enhance the conversion process. The effects of metal modifications on the active radicals, organic phase yields, properties and compositions, and catalyst coking rates were explored. The results showed that under the action of NTP, the Ru and Ti modified species enhanced the formation of active radicals and activated more volatiles into the same radical scale, contributing to the integration of mixed vapors. Particularly, the yield and high heating value of organic phase by using TiHZ5 reached 58.73% and 38.73MJ/kg, respectively. The modification of Ru, Ti and Sn significantly increased the relative contents of aromatic hydrocarbons in the organic phase, which were increased by 109.15%, 208.55% and 52.52%, respectively, resulting in a decrease in the effective hydrogen to carbon ratio distribution of the product. In addition, the coking rates of Ru, Ti and Sn modified HZSM-5 were decreased from 12.88% to 9.44%, 4.95% and 10.91%, respectively. And Ti modification significantly improved the stability of catalyst. In general, under the action of NTP, Ti modified HZSM-5 had higher conversion efficiency and higher catalytic stability.

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樊永勝,侯光喜,熊永蓮,蔡憶昔,趙衛(wèi)東.基于NTP的生物質(zhì)熱解氣間接加氫提質(zhì)試驗(yàn)研究[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2021,52(7):322-328. FAN Yongsheng, HOU Guangxi, XIONG Yonglian, CAI Yixi, ZHAO Weidong. Experiment on Indirect Hydrogenation Upgrading of Biomass Pyrolysis Vapors Based on NTP[J]. Transactions of the Chinese Society for Agricultural Machinery,2021,52(7):322-328.

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  • 收稿日期:2020-08-05
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  • 在線發(fā)布日期: 2021-07-10
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